Product ID:AUTOMOTIVE GASOLINE: GASOLINE CONTAINING ET
MSDS Date:02/01/1990
FSC:9130
NIIN:01-090-1092
MSDS Number: BRPGK

FARMERS UNION CENTRAL EXCHANGE INC.

5500 CENEX DR CENEX MS 530
ST PAUL, MN 55164-0089
US

Emergency Phone: 612-451-5151/800-424-9300(CHEMTREC)

Info Phone: 612-451-5151

Cage: 5Z134

FARMERS UNION CENTRAL EXCHANGE INC

64089 ST PAUL, MN 55164-0089 US

Telephone: 612-451-5151

Cage: 5Z134

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <12%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

HYDROCARBON MIXTURE

Fraction By Weight: 50-80%

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3.99%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: <2%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-20%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 10%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9293

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
DERMATITIS. BENZENE IS A CONFIRME D CARCINOGEN AND MAY PRODUCE
BLOOD CHANGES.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES/SKIN:INTENSE IRRITATION, DERMATITIS.
INHALATION:INTENSE IRRITATION, HEADACHE, NAUSEA, WEAKNESS,
SEDATION, AND UNCONSCIOUSNESS. INGESTION: IRRITATION TO INTESTINES,
INDEBRIATION, DROWSINESS. ASPIR ATION INTO LUNG AFTER INGESTION MAY
RESULT IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY
MFR.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING.SEE DOCTOR IMMEDIATELY. NOTE TO PHYSICIAN: GASTRIC LAVAGE
USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR DISCRETION

Flash Point Method:TCC
Flash Point:-50F,-46C
Autoignition Temp:Autoignition Temp Text:536F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:CARBON DIOXIDE, ALCOHOL FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO
COOL FIRE EXPOSED CONTAINERS & TO DISPERSE VAPORS OR FLUSH LIQUID
FROM AREAS OF IGNITION EXPOSURE.
Unusual Fire/Explosion Hazard:FIRE FIGHTERS SHOULD USE NIOSH APPROVED
SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE
WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.

Spill Release Procedures:REVIEW FIRE & EXPLOSION HAZARDS. USE
APPROPRIATE PROTECTIVE EQUIPMENT. REPORT SPILLS AS REQUIRED. REMOVE
IGNITION SOURCES. CONTAIN SPILL DO NOT ALLOW TO ENTER SEWER OR
SURFACE WATER. RECOVER AS MUCH P RODUCT AS POSSIBLE; ABSORB THE
REMAINDER.

Handling and Storage Precautions:OSHA CLASS IA. STORE IN COOL,DRY,WELL
VENTILATED AREA,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS. KEEP CLOSED WHEN NOT IN USE.
Other Precautions:NO SMOKING IN AREAS OF USE. PREVENT STATIC
SPARKS,BOND AND GROUND CONTAINERS DURING TRANSFER. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE. USE WATER SPRAY TO DISPERSE VAPORS
& PROTECT WORKERS FROM AN UNIG NITED SPILL.

Respiratory Protection:APPROPRIATE NIOSH/MSHA RESPIRATOR SHOULD BE
AVAILABLE FOR NON-ROUTINE & EMERGENCY USE ABOVE THE TLV.
Ventilation:GENERAL AND/OR LOCAL EXHAUST VENTILATION TO KEEP EXPOSURES
BELOW THE TLV. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:NEOPRENE OR RUBBER
Eye Protection:SAFETY GOGGLES OR FACE SHIELDYGLASSES WI
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,
PROTECTIVE CLOTHING TO PREVENT PROLONGED/REPEATED SKIN CONTACT.
CHANGE CLOTHES DAILY
Work Hygienic Practices:PROVIDE SUITABLE TRAINING FOR THOSE WORKING
WITH THIS MATERIAL.
Supplemental Safety and Health
KEY2:KT

HCC:F1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:275-475 MM
Vapor Density:3.0-4.0
Spec Gravity:0.65-0.75
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, MOBILE LIQUID WITH CHARACTERISTIC GASOLINE
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS ** FORMS EXPLOSIVE MIXTURES WITH AIR
Stability Condition to Avoid:UNDUE EXPOSURE TO AIR, HIGH HEAT, OPEN
FLAMES, STATIC ELECTRICITY AND OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON OXIDES AND OTHER TOXIC
MATERIALS
Conditions to Avoid Polymerization:"N/A" WILL NOT OCCUR

Waste Disposal Methods:BURN SCRAP MATERIAL IN AN APPROVED INCINERATOR.
BURN CONTAMINATED LIQUID BY SPRAYING INTO AND INCINERATOR FOLLOW
CURRENT FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.